Gao Xiaohong,Yang Yang,Zhang Wei,Jia Wei,Li Jinshan,Tian Chengming,Zhang Yanjiao,Yang Lingyu,He Linhua
Visible and Near-Infrared Reflectance Spectroscopy (VNIRS) has extensively been used to estimate soil total nitrogen (TN) concentration,and can provide a rapid,convenient method for quantitatively obtaining soil TN content in a wide range of areas.In this study,we evaluated the prediction ability of Visible and Near-Infrared Reflectance Spectroscopy (VNIRS) for estimating soil TN in the Sanjiang Yuan regions of Qinghai province.Firstly,we collected about 146 surface soil samples (0~30 cm),including four soil types during the period from August 7 to 17 of 2012 in Yushu and Maduo counties;secondly,we respectively measured soil reflectance spectrum by ASD FieldSpec 4 portable spectrometer (Analytical Spectral Devices,Inc.,Boulder Colorado,2012) with the spectral range of 350~2 500 nm,and soil TN by using Vario EL Ⅲ element analyzer of ELEMENTAR Inc.in the laboratory;and then we respectively adopted PLSR and BPNN models to relate soil TN to raw spectral reflectance and its four pre-processing transformations for the overall soil samples and each soil types samples.The results showed that the average coefficients of determination(R2) of calibration and validation for BPNN are respectively 0.87 and 0.81 with the mean RPDval of 2.28,whereas those of PLSR model are 0.75,0.72 and 1.95 respectively,which suggest that BPNN has a better prediction ability than PLSR as a whole;The combination of BPNN and the raw reflectance spectrum (REF) and its all pre-processing transformations performed a good or closer good prediction ability for different and overall soil types;whereas the combination of PLSR model and REF,Log(1/R),BD produced a rough or good prediction ability for estimating TN,however,FDR and SDR with poor prediction ability,especially SDR (R2 cal<0.5,R2val<0.5,RPDval=1.10~1.27) hasnt the ability to predict soil TN;As a whole,TN estimating from the overall soil samples can produce more stability prediction accuracies than single soil types,whereas that from single soil type samples can reflect the difference among soil types;BPNN model accuracies are superior to those of PLSR model,but PLSR has stronger operability,and can show the difference among soil types,and different among transformation indicators as well as.